Effects of Si-Si ?-Bonds on Stability of Adjacent Benzylic Cations

DOI: 10.1246/cl.1990.1937

Source and publish data:

Chemistry Letters p. 1937 - 1940 (1990)

Update date:2022-09-26

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Authors:

Shimizu, Nobujiro

Kinoshita, Chieko

Osajima, Erika

Tsuno, Yuho

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Article abstract of DOI:10.1246/cl.1990.1937

Solvolytic formation of α-pentamethyldisilanylbenzyl cation is about 7 kcal/mol energetically more favorable than that of α-trimethylsilylbenzyl cation from the corresponding bromides in 97percent TFE.

Full text of DOI:10.1246/cl.1990.1937

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