Spectroscopy of the NaH, NaD, KH, and KD X 1Σ+ ground state by laser excited fluorescence in a high frequency discharge

Article abstract of DOI:10.1063/1.440721

By laser excited fluorescence of the hydrides obtained in a discharge, the ground state vibrational levels of NaH, NaD, KH, and KD, have been observed up to v = 15, 20, 14, and 16, respectively , instead of v = 8,2 , 4, and 4 by conventional spectroskopy.Experimental values of G_v , B_v , and D_v are obtained.Spectroscopic parameters and RKR potential curves are calculated.In NaH and NaD, a comparison can be made with ab initio calculations.

Full text of DOI:10.1063/1.440721

1 +
Spectroscopy of the NaH, NaD, KH, and KD X
fluorescence in a high frequency discharge
ground state by laser excited
Σ
Marc Giroud and Odette Nedelec
Citation: The Journal of Chemical Physics 73, 4151 (1980); doi: 10.1063/1.440721
View online: http://dx.doi.org/10.1063/1.440721
View Table of Contents: http://aip.scitation.org/toc/jcp/73/9
Published by the American Institute of Physics