Reaction of aminothiazole-oximetosylates with thiols

DOI: 10.1016/S0040-4020(01)96053-3

Source and publish data:

Tetrahedron p. 10045 - 10052 (1991)

Update date:2022-08-05

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Authors:

Rezessy Rezessy

Toldy Toldy

Horvath Horvath

Sohar Sohar

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Article abstract of DOI:10.1016/S0040-4020(01)96053-3

The reaction of ethyl 2-(2-aminothiazol-4-yl)-2-tosyloxyiminoacetate and its tritylamino analogue with thiols gave ethyl 2-(5-R-thio-2-amino- or tritylamino-thiazol-4-yl)-2-oxoacetate derivatives. Structures were elucidated by ir, ¹H-, ¹³C-nmr and mass spectroscopy. A reaction mechanism is suggested.

Full text of DOI:10.1016/S0040-4020(01)96053-3

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Product name:ethyl 2-(5-ethylthio-2-aminothiazol-4-yl)-2-oxoacetate

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