?-Conjugated Systems with Unique Electronic Structure: A Case of "Planarized" 1,3-Connected Polyarylmethyl Carbodianion and Stable Triplet Hydrocarbon Diradical

DOI: 10.1021/jo00032a030

Source and publish data:

Journal of Organic Chemistry p. 1760 - 1767 (1992)

Update date:2022-08-15

Topics: Synthesis Electronic structure Aryl group X-ray crystallography Spectroscopic Characterization Reactivity Studies Spin State Diradical 1,3-Connected DFT (Density Functional Theory) Resonance stabilization Molecular orbital theory EPR (Electron Paramagnetic Resonance)

Authors:

Rajca, Andrzej

Utamapanya, Suchada

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00032a030

The effect of "planarization" on ?-conjugated 1,3-connected polyarylmethyls in connection with the electronic structure and magnetic properties is examined.The synthesis, ESR and UV-vis spectroscopy, voltammetry, and magnetic studies of triplet diradical

Full text of DOI:10.1021/jo00032a030

Products guided by the article

Product name:2,10-Di-tert-butyl-5,7-bis-(4-tert-butyl-phenyl)-12,12,14,14-tetramethyl-5,7,12,14-tetrahydro-pentacene

Cas No:138956-20-4

R&D Labs maybe for 138956-20-4

Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
LIDE PHARMACEUTICALS LIMITED

website:http://www.lidepharma.com

Contact:

Address:Chungking Express Nos.36 Nathan Road，Kowloon, HK
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China

Relevant to this article

Ethyl 1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylates by a tandem S _NAr-addition-elimination reaction

Doi:10.1002/jhet.917
(2012)
Copper-catalyzed intermolecular oxidative cyclization of haloalkynes: Synthesis of 2-halo-substituted imidazo [1,2-α]pyridines, imidazo [1,2-α]pyrazines and imidazo [1,2-α]pyrimidines

Doi:10.1002/adsc.201300157
(2013)
Crystal structures and phase-transition dynamics of cobaltocenium salts with bis(perfluoroalkylsulfonyl)amide anions: Remarkable odd-even effect of the fluorocarbon chains in the anion

Doi:10.1002/chem.201300186
(2013)
Synthesis of 1,2,3-triazolyl nucleoside analogs as potential anti-influenza A (H3N2 subtype) virus agents

Doi:10.1002/ardp.201300260
(2014)
Rhodium-catalyzed carbonylative [3 + 2 + 1] cycloaddition of alkyne-tethered alkylidenecyclopropanes to phenols in the presence of carbon monoxide

Doi:10.1021/ol5015224
(2014)
Specific cell surface protein imaging by extended self-assembling fluorescent turn-on nanoprobes

Doi:10.1021/ja304239g
(2012)

Article Doi