?-Conjugated Systems with Unique Electronic Structure: A Case of "Planarized" 1,3-Connected Polyarylmethyl Carbodianion and Stable Triplet Hydrocarbon Diradical

DOI: 10.1021/jo00032a030

Source and publish data:

Journal of Organic Chemistry p. 1760 - 1767 (1992)

Update date:2022-08-15

Topics: Synthesis Electronic structure Aryl group X-ray crystallography Spectroscopic Characterization Reactivity Studies Spin State Diradical 1,3-Connected DFT (Density Functional Theory) Resonance stabilization Molecular orbital theory EPR (Electron Paramagnetic Resonance)

Authors:

Rajca, Andrzej

Utamapanya, Suchada

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Article abstract of DOI:10.1021/jo00032a030

The effect of "planarization" on ?-conjugated 1,3-connected polyarylmethyls in connection with the electronic structure and magnetic properties is examined.The synthesis, ESR and UV-vis spectroscopy, voltammetry, and magnetic studies of triplet diradical

Full text of DOI:10.1021/jo00032a030

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