Russian Chemical Bulletin p. 890 - 896 (1995)
Update date:2022-08-04
Topics: Synthesis Yield NMR spectroscopy Mechanism Olefins Reaction Conditions Experimental terms 1-aryl-2-bromodiazene 1-oxides Novel reaction
Churakov, A. M.
Tyurin, A. Yu.
Goncharova, E. L.
Ioffe, S. L.
Strelenko, Yu. A.
Tartakovsky, V. A.
The addition of 1-aryl-2-bromodiazene 1-oxides to olefins yields 1-aryl-2-(2-bromoalkyl)diazene 1-oxides (4).A radical mechanism of the reaction has been suggested.Compounds 4 decompose to give bromohydrazones of formaldehyde and aldehydes.The structural factors that affect the rate of this process are discussed.
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