10.1002/cplu.201800214
ChemPlusChem
FULL PAPER
Polymer synthesis. GP4 for CMPs C-1
– Sn-1: The respective
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tetrahedral monomer (1.0 eq) was dissolved in a degassed mixture of
toluene and tiethylamine. Then, 1,4-diiodobenzene (2.0 eq) and
bis(triphenylphosphine)palladium(II) dichloride (2 mol%) were added. The
reaction mixture was stirred at 100 °C overnight and filtered. The solid was
pestled in a mortar, washed with methanol and subjected to Soxhlet
extraction from methanol overnight. The resulting powder was pestled in a
mortar again and dried in vacuo to yield the respective polymer. See
Supporting Information for analytical data of C-1 – Sn-1.
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40 °C for 3 d and filtered. The solid was pestled in a mortar, washed with
methanol and subjected to Soxhlet extraction from methanol overnight.
The resulting powder was pestled in a mortar again and dried in vacuo to
yield the respective polymer. See Supporting Information for analytical
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We thank Prof. M. Mastalerz and Sven Elbert for sorption analysis
instrument time and supportive discussions. F. L. Geyer
expresses his gratitude to the German National Academic
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Keywords: tetrahedral connectors • microporous polymers • 3D
networks • structure-property-relationship
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