Canadian Journal of Chemistry p. 1883 - 1893 (1994)
Update date:2022-08-03
Topics:
Liu
Li
Browne
The stereofacially differentiated enone aldehyde 11 was chosen to study the effects of steric and electronic influence on the Diels-Alder reaction. Under Lewis acid catalysis, 11 adds to dienes at low temperatures at a reasonable rate. Yields of desired chiral adducts are good to high with zinc chloride and boron trifluoride etherate catalysis. In all cases only products of addition to the Re face of general type 27 were observed. The regiochemistry of the adducts is exclusively that predicted by the ortho and para rules. The stereochemistry shows a very high selectivity in favour of aldehyde-endo transition state products. Unusual by-products were also obtained in some examples and mechanisms of these unexpected reactions are discussed.
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