Tricarbonylchromium(0) Complexes in Organic Synthesis: A Highly Anti-Selective Asymmetric Aldol Reaction with O-Silyl Ketene O,S-Acetals

DOI: 10.1021/jo00033a025

Source and publish data:

Journal of Organic Chemistry p. 2034 - 2040 (1992)

Update date:2022-08-03

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Authors:

Mukai,Chisato

Miyakawa, Motonori

Mihira, Ado

Hanaoka, Miyoji

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Article abstract of DOI:10.1021/jo00033a025

Treatment of optically pure (+)-tricarbonylchromium (0), (+)-1, with O-silyl ketene O,S-acetals 4c-f afforded, after decomplexation, the (-)-5c-f, while an antipode, (-)-1, prodvided the (+)-anti ones (+)-5c-f.Optical puity

Full text of DOI:10.1021/jo00033a025

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Product name:ethyl (2R*,3R*)-3-hydroxy-2-methyl-3-<2-(trimethylsilyl)phenyl>propionate

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