Ligand-assisted asymmetric synthesis. I. Modelling of chiral auxiliaries for the diastereoselective Diels-Alder reaction

DOI: 10.1016/0040-4039(91)85035-4

Source and publish data:

Tetrahedron Letters p. 7043 - 7046 (1991)

Update date:2022-08-04

Topics:

Authors:

Gras Gras

Pellissier

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Article abstract of DOI:10.1016/0040-4039(91)85035-4

The chiral auxiliaries derived from threitol are particularly well designed to form chelated complexes with Lewis acids. The diastereoselective Diels-Alder addition to cyclopentadiene is the consequence of a roof shaped semirigid conformation, as demonstr

Full text of DOI:10.1016/0040-4039(91)85035-4

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