Pederin: The metallated dihydropyran approach. Stereoselective reduction of N-acylimidates via rhodium-catalysed hydroboration

DOI: 10.1055/s-1991-28418

Source and publish data:

Synthesis p. 1191 - 1200 (1991)

Update date:2022-07-29

Topics:

Authors:

Kocienski

Jarowicki

Marczak Marczak

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1991-28418

A synthesis of the insect toxin pederin (1) based upon the union of metallated dihydropyran 8 with the oxamate ester derivative 9 is described. Noteworthy features include (a) a new method for the construction of metallated dihydropyrans which tolerates h

Full text of DOI:10.1055/s-1991-28418

Products guided by the article

Product name:N-{(S)-[(2S,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((S)-2,3-dimethoxy-propyl)-5,5-dimethyl-tetrahydro-pyran-2-yl]-methoxy-methyl}-2-((4S,5R,6R)-5,6-dimethyl-4-phenylselanylmethyl-5,6-dihydro-4H-pyran-2-yl)-2-oxo-acetamide

Cas No:139301-85-2

R&D Labs maybe for 139301-85-2

Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.

Contact:+86 532 80861829

Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China

Relevant to this article

Synthesis of 5,6-disubstituted thieno[2,3-d]pyrimidines from 4-chloropyrimidines

Doi:10.3987/COM-12-12463
(2012)
Stereodefined construction of trisubstituted alkenes by direct coupling reaction of allylating agents, alkynes, and organoboranes

Doi:10.1002/chem.201201138
(2012)
New synthesis and promising neuroprotective role in experimental ischemic stroke of ONO-1714

Doi:10.1016/j.ejmech.2012.05.031
(2012)
Iron triflate catalyzed reductive amination of aldehydes using sodium borohydride

Doi:10.1016/j.tetlet.2012.06.018
(2012)
A Novel Approach to α-Silylmethylene-β-lactams via Rh-catalyzed Silylcarbonylation of Propargylamine Derivatives

Doi:10.1016/0040-4039(91)80126-Q
(1991)
Mechanistic insight into the anomalous syn-selectivity observed during the addition of allenylboronates to aromatic aldehydes

Doi:10.1246/cl.2011.1044
(2011)

Article Doi