Pederin: The metallated dihydropyran approach. Stereoselective reduction of N-acylimidates via rhodium-catalysed hydroboration

DOI: 10.1055/s-1991-28418

Source and publish data:

Synthesis p. 1191 - 1200 (1991)

Update date:2022-07-29

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Authors:

Kocienski

Jarowicki

Marczak Marczak

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Article abstract of DOI:10.1055/s-1991-28418

A synthesis of the insect toxin pederin (1) based upon the union of metallated dihydropyran 8 with the oxamate ester derivative 9 is described. Noteworthy features include (a) a new method for the construction of metallated dihydropyrans which tolerates h

Full text of DOI:10.1055/s-1991-28418

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