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Pederin: The metallated dihydropyran approach. Stereoselective reduction of N-acylimidates via rhodium-catalysed hydroboration

DOI: 10.1055/s-1991-28418

Source and publish data:

Synthesis p. 1191 - 1200 (1991)

Update date:2022-07-29

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Authors:

KocienskiKocienski

JarowickiJarowicki

MarczakMarczak

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Article abstract of DOI:10.1055/s-1991-28418

A synthesis of the insect toxin pederin (1) based upon the union of metallated dihydropyran 8 with the oxamate ester derivative 9 is described. Noteworthy features include (a) a new method for the construction of metallated dihydropyrans which tolerates h

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Full text of DOI:10.1055/s-1991-28418

Products guided by the article

Product name:N-{(S)-[(2S,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((S)-2,3-dimethoxy-propyl)-5,5-dimethyl-tetrahydro-pyran-2-yl]-methoxy-methyl}-2-((4S,5R,6R)-5,6-dimethyl-4-phenylselanylmethyl-5,6-dihydro-4H-pyran-2-yl)-2-oxo-acetamide

Cas No:139301-85-2

139301-85-2

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