Captodative α,β-unsaturated oxazolines as dienophiles in the asymmetric Diels-Alder reaction

DOI: 10.1016/S0957-4166(00)80022-1

Source and publish data:

Tetrahedron Asymmetry p. 1223 - 1230 (1991)

Update date:2022-08-02

Topics:

Authors:

Langlois, Yves

Pouilhes, Annie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(00)80022-1

Captodative oxazoline derivative 5a gave rise to four-cycloadducts 6, 7, 8 and 9 in the presence of trifluoroacetic anhydride and cyclopentadiene.Hydrolysis of 6 led to α-phenylthio carboxylic acid 14.

Full text of DOI:10.1016/S0957-4166(00)80022-1

Products guided by the article

Product name:(1S,2R,3S,4R)-4,7,7-Trimethyl-3-methylamino-bicyclo[2.2.1]heptan-2-ol

Cas No:139345-20-3

R&D Labs maybe for 139345-20-3

Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Shanghai Science Peptide Biological Technology Co.,ltd

website:http://www.scipeptide.com

Contact:+86-21-51099675

Address:No.8 Changyang Rd
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA

Relevant to this article

α-aminoxylation of ketones and β-chloro-α-aminoxylation of enones with tempo and chlorocatecholborane

Doi:10.1021/ol301979b
(2012)
Synthesis of α-(1->2)-, α-(1->3)-, α-(1->4)-, and α-(1->5)-C-Linked Disaccharides through 2,3,4,6-Tetra-O-acetylglucopyranosyl Radical Additions to 3-Methylidene-7-oxabicyclo<2.2.1>heptan-2-one Derivatives

Doi:10.1021/jo00033a032
(1992)
Synthesis of dibenzocyclohepten-5-ones by electrophilic iodocyclization of 1-([1,1′-Biphenyl]-2-yl)alkynones

Doi:10.1021/jo5001803
(2014)
Synthesis of α-vinylidene-β-lactams by the palladium-catalyzed carbonylation of 4-amino-2-alkynyl carbonates

Doi:10.1016/0040-4039(91)80564-M
(1991)
An orthomanganation route to 2-substituted derivatives of N-methyl-1,8-naphthalimide

Doi:10.1016/j.jorganchem.2012.06.035
(2012)
Chemoselective Synthesis of 2,2′-Arylmethylene bis-(3-Hydroxy-2-cyclohexenes) ("Tetraketones") in Hexafluoro-2-propanol

Doi:10.1080/00304948.2016.1127102
(2016)

Article Doi