Tetrahedron Letters p. 6151 - 6154 (1990)
Update date:2022-09-26
Topics:
Stevenson
Peters
Reidy
EPR analyis shows that the equilibrium isotope effect upon the equilibrium constant for electron transfer between isotopic isomers is much larger in [6]annulene (i.e. C6H6-·+13C6D6 = C6H6 + 13C6D6-·) than in the [8]annulene systems (i.e. C8H8-· + 13C8D8 = C8H8 + 13C8D8-·). This is due to the effects of aromaticity.
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(1991)
