The Catalytic Pinacol Rearrangement of 1,2-Diols Using an Antimony(V)Salt

DOI: 10.1246/cl.1992.81

Source and publish data:

Chemistry Letters p. 81 - 84 (1992)

Update date:2022-07-30

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Authors:

Harada, Tsunehiro

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1992.81

In the presence of a catalytic amount of antimony(V)chloride or antimony(V)salt generated from antimony(V)chloride and silver hexafluoroantimonate, the pinacol rearrangement of several 1,2-diols or their trimethylsilyl ethers proceeds smoothly to give the corresponding ketones in good yields.

Full text of DOI:10.1246/cl.1992.81

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