DIASTEREOSELECTIVE ADDITION OF ORGANOMETALLIC REAGENTS TO CHIRAL IMINES AND 1,3-OXAZOLIDINES

DOI: 10.1016/0040-4039(92)88059-E

Source and publish data:

Tetrahedron Letters p. 235 - 238 (1992)

Update date:2022-08-05

Topics:

Authors:

Higashiyama, Kimio

Inoue, Hiroaki

Takahashi, Hiroshi

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Article abstract of DOI:10.1016/0040-4039(92)88059-E

The reaction of MeLi or MeMgBr with chiral aromatic imines and 2-aryl-1,3-oxazolidines derived from (R)-phenylglycinol afforded with good diastereoselectivity (R,R)-amines from imines, but the (R,S)-amines from 1,3-oxazolidines, respectively.

Full text of DOI:10.1016/0040-4039(92)88059-E

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