Highly stereoselective addition reactions of metallated trans-1,3-dithiane-1,3-dioxide to aldehydes

DOI: 10.1016/0040-4039(91)80580-Y

Source and publish data:

Tetrahedron Letters p. 7743 - 7746 (1991)

Update date:2022-07-30

Topics:

Authors:

Aggarwal, Varinder K.

Franklin, Richard J.

Rice, Martin J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80580-Y

The sodium anion of trans-1,3-dithiane-1,3-dioxide reacts with unhindered aromatic and heteroaromatic aldehydes to give adducts with 95:5 to 97:3 diastereoselectivity.

Full text of DOI:10.1016/0040-4039(91)80580-Y

Products guided by the article

Product name:1-(RS)-3-(RS)-α-(SR)-α-(4-Nitrophenyl)-1,3-dioxo-1,3-dithiane-2-methanol

Cas No:139578-25-9

R&D Labs maybe for 139578-25-9

Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao

Relevant to this article

Platinum(II) complexes of cyclic triphosphenium ions: A ³¹P NMR spectroscopic and computational study

Doi:10.1021/ic3011663
(2012)
Diastereo- and enantioselective conjugate addition of 3-chlorooxindoles to nitroalkenes catalyzed by binaphthyl-modified organocatalyst

Doi:10.1002/bkcs.10264
(2015)
Chemistry of Molybdenum. Part 8. Syntheses, Spectroscopy and Electrochemical Properties of Molybdenum Complexes containing Dithioacid Ligands

Doi:10.1039/DT9920000269
(1992)
Doi:10.1016/S0277-5387(00)83271-4
(1992)
TAPP analogs containing β³-homo-amino acids: Synthesis and receptor binding

Doi:10.1002/psc.2433
(2012)
Extended benzodifuran-furan derivatives as example of π-conjugated materials obtained from sustainable approach

Doi:10.1016/j.tet.2012.07.079
(2012)

Article Doi