Highly stereoselective addition reactions of metallated trans-1,3-dithiane-1,3-dioxide to aldehydes

DOI: 10.1016/0040-4039(91)80580-Y

Source and publish data:

Tetrahedron Letters p. 7743 - 7746 (1991)

Update date:2022-07-30

Topics:

Authors:

Aggarwal, Varinder K.

Franklin, Richard J.

Rice, Martin J.

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Article abstract of DOI:10.1016/0040-4039(91)80580-Y

The sodium anion of trans-1,3-dithiane-1,3-dioxide reacts with unhindered aromatic and heteroaromatic aldehydes to give adducts with 95:5 to 97:3 diastereoselectivity.

Full text of DOI:10.1016/0040-4039(91)80580-Y

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Product name:1-(RS)-3-(RS)-α-(SR)-α-(4-Nitrophenyl)-1,3-dioxo-1,3-dithiane-2-methanol

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