A facile chemoenzymatic route to optically active 4,5-disubstituted-2E-hexenoate derivatives. I

DOI: 10.1248/cpb.41.55

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 55 - 63 (1993)

Update date:2022-08-04

Topics: Optically active Facile Experimental Route Chemoenzymatic

Authors:

Akita Akita

Umezawa Umezawa

Takano Takano

Ohyama Ohyama

Matsukura

Oishi Oishi

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Article abstract of DOI:10.1248/cpb.41.55

The reaction of (±) methyl 4,5-trans-epoxy-2E-hexenoate (2) with aromatic nucleophiles having an electron-donating group in the presence of BF₃ · Et₂O gave the 4,5-anti-5-hydroxy-4- or/and 2,5-anti-5-hydroxy-2-substituted products. T

Full text of DOI:10.1248/cpb.41.55

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