Thiadiazatrimethylenemethane and N,N',P-Triphenylphosphonothioic Diamide Complexes of Platinum(II)

DOI: 10.1039/DT9920000059

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 59 - 66 (1992)

Update date:2022-08-03

Topics:

Authors:

Henderson, William

Kemmitt, Raymond D. W.

mason, Simon

Moore, Mark R.

Fawcett, John

Russell, David R.

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Article abstract of DOI:10.1039/DT9920000059

Reaction od N,N'-diphenylthiourea with cis- 2 = Ph2PCH2Ch2PPh2 (dppe)> in the presence of silver(I) oxide gives the thiadiazatrimethylenemethane complexes , an X-ray study on establishing the presence of a flat -Pt-S-C-N- ring.Related -Pt-S-P-N- ring complexes which contain a reactive nucleophilic P=NPh group are formed upon treatment of PhP(S)(Ph)NHPh with cis- 2 = dppe, Ph2P(CH2)3PPh2 or Ph2P(CH2)4PPh2> and potassium hydroxide.Treatment of with MeI afforded an aminophosphonium salt, whilst with substrates containing either C=O or C=S functionalities new complexes of the type or were formed respectively.

Full text of DOI:10.1039/DT9920000059

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