THE SYNTHESIS OF CYCLODECANE DERIVATIVES BY INTRAMOLECULAR ALKYLATION OF AN α-PHENYLSULFENYL KETONE

DOI: 10.1016/S0040-4020(01)80576-7

Source and publish data:

Tetrahedron p. 33 - 44 (1992)

Update date:2022-08-03

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Authors:

Caine, Drury

Stanhope, Bruce

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Article abstract of DOI:10.1016/S0040-4020(01)80576-7

The acyclic ω-tosyloxy-α-phenylsulfenyl ketone 1a, derived from R-(-)-carvone, underwent intramolecular alkylation to give the cyclodecenone derivative 2a in good yield. Oxidation of the sulfide to the sulfoxide and thermal elimination of phenylsulfinic a

Full text of DOI:10.1016/S0040-4020(01)80576-7

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