Tetrahedron Letters p. 535 - 538 (1992)
Update date:2022-08-04
Topics:
O'Sullivan, Patrick J.
Moreno, Rafael
Murphy, William S.
The new bromoquinone-enamine annulation was successfully extended to acyclic enamino ketones resulting in a new synthesis of the ABC framework 7 of kinamycins and when applied to cyclic enamino ketones 8a-c the first synthesis of their ABCD ring system.Smooth aromatisation of compounds 4b,d to 9a,b respectively was effected with DDQ. - Key Words: regiospecific annulation, metal catalysed; kinamycin; tetrahydrobenzocarbazole
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Doi:10.1126/science.aao0270
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(1992)
