Addition of Amino Amides to Vinyl Vicinal Tricarbonyls. Formation of Tricyclic 3-Azadethiacephams

DOI: 10.1021/jo00035a019

Source and publish data:

Journal of Organic Chemistry p. 2641 - 2645 (1992)

Update date:2022-08-05

Topics:

Authors:

Wasserman, Harry H.

Henke, Susan L.

Nakanishi, Eiji

Schulte, Gayle

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00035a019

Amino amides react as trinucleophiles with vinyl vicinal tricarbonyl esters.Reaction of the primary amino group takes place at the β-position of the α,β-unsaturated ketone along with addition to the central carbonyl group.In a third-stage reaction, the am

Full text of DOI:10.1021/jo00035a019

Products guided by the article

Product name:7-<1-<1-<(tert-butyldimethylsilyl)oxy>ethyl>>-6-methyl-9a-carbobenzoxy-1,8-dioxoazetidino<1,2-c>perhydropyrrolo<1,2-a>pyrimidine

Cas No:139976-61-7

R&D Labs maybe for 139976-61-7

Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China

Relevant to this article

Highly efficient and selective deprotection method for prenyl, geranyl, and phytyl ethers and esters using borontrifluoride-etherate

Doi:10.1080/00397911.2011.589561
(2013)
Hydrogen bonding directed intermolecular cope-type hydroamination of alkenes

Doi:10.1021/ol3023177
(2012)
Catalytic asymmetric claisen rearrangement of enolphosphonates: Construction of vicinal tertiary and all-carbon quaternary centers

Doi:10.1002/anie.201203092
(2012)
1,3-Bis(trimethylsilyl)propene as 1,3- and 3,3-Propene Dianion Synthons. Reactions of 2-Aryl-1,3-bis(trimethylsilyl)propenes with Electrophiles

Doi:10.1021/jo00035a046
(1992)
Silicon acceleration of a tandem alkene isomerization/electrocyclic ring-opening of 2-methyleneoxetanes to α,β-unsaturated methylketones

Doi:10.1021/jo4014645
(2013)
An efficient synthesis of thiazolidine-4-ones with antitumor and antioxidant activities

Doi:10.1002/jhe.641
(2012)

Article Doi