Addition of Amino Amides to Vinyl Vicinal Tricarbonyls. Formation of Tricyclic 3-Azadethiacephams

DOI: 10.1021/jo00035a019

Source and publish data:

Journal of Organic Chemistry p. 2641 - 2645 (1992)

Update date:2022-08-05

Topics:

Authors:

Wasserman, Harry H.

Henke, Susan L.

Nakanishi, Eiji

Schulte, Gayle

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Article abstract of DOI:10.1021/jo00035a019

Amino amides react as trinucleophiles with vinyl vicinal tricarbonyl esters.Reaction of the primary amino group takes place at the β-position of the α,β-unsaturated ketone along with addition to the central carbonyl group.In a third-stage reaction, the am

Full text of DOI:10.1021/jo00035a019

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