Models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes: Salts and zwitterions from 1-dimethylamino- naphthalene-8-carbaldehyde

DOI: 10.1039/c2ob25929j

Source and publish data:

Organic and Biomolecular Chemistry p. 7763 - 7779 (2012)

Update date:2022-08-03

Topics:

Authors:

Lari, Alberth

Pitak, Matuesz B.

Coles, Simon J.

Rees, Gregory J.

Day, Stephen P.

Smith, Mark E.

Hanna, John V.

Wallis, John D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c2ob25929j

The X-ray crystal structures of salts and zwitterionic Knoevenagel products from 1-dimethylamino-naphthalene-8-carbaldehyde show long N-C bonds between peri-groups which provide models for incomplete nucleophilic attack on a protonated carbonyl group and

Full text of DOI:10.1039/c2ob25929j

Products guided by the article

Product name:4,4-dimethyl-1-(1′,1′-dimethyl-1′,2′-dihydrobenzo[cd]indol-1′-ium-2′-yl)-2,6-dioxocyclohexan-1-ide

Cas No:1400937-56-5

R&D Labs maybe for 1400937-56-5

Global United Biotechnology Inc.

Contact:+86-21-61618568

Address:Room 309, Building 6, NO.135, Jinyu Road, Pudong
Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China

Relevant to this article

First Total Synthesis of a Natural Thapsane

Doi:10.1039/c39910001693
(1991)
Synthesis of 2,4-diamino-5,10-dideaza nonclassical antifolates

Doi:10.1002/jhet.5570280717
(1991)
Chemoenzymatic Approach to Carbohydrate-Derived Analogoues of Platelet-Activating Factor

Doi:10.1021/jo00033a043
(1992)
Synthesis of nigricanin via intramolecular biaryl coupling reaction of functionalized phenyl benzoate

Doi:10.3987/COM-13-12847
(2013)
Preparation of heptakis(6-O-(p-tosyl))-β-cyclodextrin and heptakis(6-O-(p-tosyl))-2-O-(p-tosyl)-β-cyclodextrin and their conversion to heptakis(3,6-anhydro)-β-cyclodextrin

Doi:10.1248/cpb.39.2505
(1991)
Stereoselective Synthesis of Trifluoromethylated Compounds with Controlled Adjacent Tertiary Carbons by Michael Addition to (E)-3-(Trifluoromethyl)acrylates

Doi:10.1021/jo00119a013
(1995)

Article Doi