Journal of Organometallic Chemistry p. 153 - 158 (1992)
Update date:2022-07-29
Topics:
Albertsen, Joerg
Steudel, Ralf
The halides (C6H5)2SiCl2, (C6H5)2GeBr2, and (C6H5)2SnCl2, react with Li2S and (η5-C5H4R)2TiCl2 (R = H, CH3) to give respectively the four-membered titanacycles Cp2TiS2Si(C6H5)2, Cp2TiS2Ge(C6H5)2, and Cp'2TiS2Sn(C6H5)2 which have been characterized by 1H NMR, mass and UV spectroscopy.The new compounds form green crystals, which react with sulphur chlorides with precipitation of (C5H4R)2TiCl2.This reaction provides a route to formerly unknown sulphur-rich heterocycles of Group 14 elements.
Anhui Redstar Pharmaceutical Corp., Ltd
Contact:+86-563-5120837
Address:Jingxian Industrial Development Zone, Anhui , China
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
ShanDong XinDa Chemical CO.,LTD(expird)
Contact:086-0311-87580543
Address:No.168, High Technology Development Zone Jinan Shandong China
Shanghai Bojing Chemical Co., Ltd.
Contact:021-37122233
Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Changzhou naidechemical Co.Ltd
Contact:+86-519-82589807
Address:NO.25,Houyang street,Jintan,Changzhou City
Doi:10.1021/ja00035a069
(1992)Doi:10.1016/j.dyepig.2012.04.001
(2012)Doi:10.1002/anie.201607223
(2016)Doi:10.1021/ol302400p
(2012)Doi:10.1055/s-0033-1339616
(2013)Doi:10.1016/j.bmcl.2016.04.095
(2016)
