Reactivities of 2-C- and 3-C-Nitro-α- and β-D-erythro-Hex-2-enopyranoside Derivatives towards Methanol and AM1 Studies upon Their Stereoselectivities

Article abstract of DOI:10.1246/bcsj.65.446

The rates of the reactions of six nitro enosides with methanol-d₄ in dimethyl sulfoxide-d₆ were determined by 1H NMR spectroscopy.Their reactivities and stereoselectivities were discussed including the results of AM1 calculations of model compounds.