Spontaneous dissociation of phosphoniumylidyl-chlorophosphines to ionic phosphenium chlorides

DOI: 10.1016/S0040-4039(00)93971-6

Source and publish data:

Tetrahedron Letters p. 471 - 474 (1992)

Update date:2022-09-26

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Authors:

Schmidpeter, Alfred

Jochem, Georg

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Article abstract of DOI:10.1016/S0040-4039(00)93971-6

The products from the replacement of two chlorofunctions of PCl₃ by a pair of phosphoniumylidyl substituents or by both a phosphoniumylidyl and an amino substituent are ionic phosphenium chlorides and not covalent chlorophosphines.

Full text of DOI:10.1016/S0040-4039(00)93971-6

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