Tetrahedron Letters p. 845 - 848 (1982)
Update date:2022-07-30
Topics:
Hoffmann, Reinhard W.
Kemper, Bruno
Addition of Z-γ-alkoxy-allylboronates 2 to aldehydes leads to the homoallylalcohls 3 and 4.Increased steric bulk both on the aldehyde part or the allylboronates causes a decrease in diastereoselectivity.The stereochemistry of the addition is established by novel synthesis of exo-brevicomine.
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