Lossen-like Rearrangement of N--O-methylsulfonylhydroxylamine with Methylamine: Retention of Configuration at Phosphorus as revealed by X-Ray Crystallography

DOI: 10.1039/c39920000227

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Journal of the Chemical Society. Chemical communications p. 227 - 229 (1992)

Update date:2022-07-30

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Authors:

Fawcett, John

Harger, Martin J. P.

Sreedharan-Menon, Ramesh

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Article abstract of DOI:10.1039/c39920000227

The diastereoisomers of the title compound 6 rearrange with high stereospecificity on treatment with MeNH2, giving PhMeCHP(O)(NHMe)NHPh in which the migrating phenyl group has been replaced by MeNH2 with retention of configuration at phosphorus.

Full text of DOI:10.1039/c39920000227

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