Formation, fragmentation, and isomerization of azatitanacycle rings supported by aryloxide ligation

DOI: 10.1021/om00041a008

Source and publish data:

Organometallics p. 1775 - 1777 (1992)

Update date:2022-08-06

Topics:

Authors:

Hill, John E.

Fanwick, Phillip E.

Rothwell, Ian P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00041a008

The ethylene complex [(Ar″O)₂Ti(η²-C₂H ₄)-(PMe₃)] (Ar″O = 2,6-diphenylphenoxide) reacts with PhCH₂N=CHPh to produce the 2-azatitanacyclopentane complex [(Ar″O)₂Ti(CH₂CH₂CHPhNCH₂Ph)], which undergoes coupling reactions with alkynes and benzonitrile to produce new azametallacycles with loss of ethylene.

Full text of DOI:10.1021/om00041a008

Products guided by the article

Product name:{((C₆H₅)2C₆H₃O)2Ti(C(C₆H₅)CHCH(C₆H₅)NCH₂C₆H₅)}

Cas No:140634-22-6

R&D Labs maybe for 140634-22-6

Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China

Relevant to this article

Ruthenium(II) Arene complexes with asymmetrical guanidinate ligands: Synthesis, characterization, and application in the base-free catalytic isomerization of allylic alcohols

Doi:10.1021/om3009124
(2012)
Carbohydrate-lipid interactions: Affinities of methylmannose polysaccharides for lipids in aqueous solution

Doi:10.1002/chem.201201222
(2012)
Synthesis and evaluation of novel 1,3,4-oxadiazole derivatives of marine bromopyrrole alkaloids as antimicrobial agent

Doi:10.1016/j.bmcl.2012.08.061
(2012)
Dual purpose S-trityl-linkers for glycoarray fabrication on both polystyrene and gold

Doi:10.1039/c2ob26118a
(2012)
Simple ultrasound-assisted synthesis of 3,4-dihydropyrimidin-2(1H)-one and 3,4-dihydropyrimidine-2(1H)-thione-fused steroidal derivatives by a three-component reaction

Doi:10.1055/s-0032-1316564
(2012)
Synthesis and Kinetic Testing of Tetrahydropyrimidine-2-thione and Pyrrole Derivatives as Inhibitors of the Metallo-β-lactamase from Klebsiella pneumonia and Pseudomonas aeruginosa

Doi:10.1111/j.1747-0285.2012.01440.x
(2012)

Article Doi