Formation, fragmentation, and isomerization of azatitanacycle rings supported by aryloxide ligation

DOI: 10.1021/om00041a008

Source and publish data:

Organometallics p. 1775 - 1777 (1992)

Update date:2022-08-06

Topics:

Authors:

Hill, John E.

Fanwick, Phillip E.

Rothwell, Ian P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00041a008

The ethylene complex [(Ar″O)₂Ti(η²-C₂H ₄)-(PMe₃)] (Ar″O = 2,6-diphenylphenoxide) reacts with PhCH₂N=CHPh to produce the 2-azatitanacyclopentane complex [(Ar″O)₂Ti(CH₂CH₂CHPhNCH₂Ph)], which undergoes coupling reactions with alkynes and benzonitrile to produce new azametallacycles with loss of ethylene.

Full text of DOI:10.1021/om00041a008

Products guided by the article

Product name:{((C₆H₅)2C₆H₃O)2Ti(C(C₆H₅)CHCH(C₆H₅)NCH₂C₆H₅)}

Cas No:140634-22-6

R&D Labs maybe for 140634-22-6

SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China

Relevant to this article

Ruthenium(II) Arene complexes with asymmetrical guanidinate ligands: Synthesis, characterization, and application in the base-free catalytic isomerization of allylic alcohols

Doi:10.1021/om3009124
(2012)
Carbohydrate-lipid interactions: Affinities of methylmannose polysaccharides for lipids in aqueous solution

Doi:10.1002/chem.201201222
(2012)
Synthesis and evaluation of novel 1,3,4-oxadiazole derivatives of marine bromopyrrole alkaloids as antimicrobial agent

Doi:10.1016/j.bmcl.2012.08.061
(2012)
Dual purpose S-trityl-linkers for glycoarray fabrication on both polystyrene and gold

Doi:10.1039/c2ob26118a
(2012)
Simple ultrasound-assisted synthesis of 3,4-dihydropyrimidin-2(1H)-one and 3,4-dihydropyrimidine-2(1H)-thione-fused steroidal derivatives by a three-component reaction

Doi:10.1055/s-0032-1316564
(2012)
Synthesis and Kinetic Testing of Tetrahydropyrimidine-2-thione and Pyrrole Derivatives as Inhibitors of the Metallo-β-lactamase from Klebsiella pneumonia and Pseudomonas aeruginosa

Doi:10.1111/j.1747-0285.2012.01440.x
(2012)

Article Doi