Formation, fragmentation, and isomerization of azatitanacycle rings supported by aryloxide ligation

DOI: 10.1021/om00041a008

Source and publish data:

Organometallics p. 1775 - 1777 (1992)

Update date:2022-08-06

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Authors:

Hill, John E.

Fanwick, Phillip E.

Rothwell, Ian P.

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Article abstract of DOI:10.1021/om00041a008

The ethylene complex [(Ar″O)₂Ti(η²-C₂H ₄)-(PMe₃)] (Ar″O = 2,6-diphenylphenoxide) reacts with PhCH₂N=CHPh to produce the 2-azatitanacyclopentane complex [(Ar″O)₂Ti(CH₂CH₂CHPhNCH₂Ph)], which undergoes coupling reactions with alkynes and benzonitrile to produce new azametallacycles with loss of ethylene.

Full text of DOI:10.1021/om00041a008

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