2,4,6-Tris(4,5-diisopropyl-1,3-dithiol-2-ylidene)cyclohexane-1,3,5-trione: Synthesis, X-Ray Crystal Structure and Amphoteric Redox Properties of a Highly Delocalised Heterocyclic ?-System

DOI: 10.1039/c39920000401

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Journal of the Chemical Society. Chemical communications p. 401 - 402 (1992)

Update date:2022-08-02

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Authors:

Coffin, Malcolm A.

Bryce, Martin R.

Clegg, William

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Article abstract of DOI:10.1039/c39920000401

The title compound 1 is synthesized by treatment of 1,3,5-trihydroxybenzene with 2-methylthio-4,5-di-n-propyl-1,3-dithiolium iodide in the presence of pyridine; the X-ray crystal structure of 1 reveals a highly delocalised ?-system with strongly bonding intramolecular S<*>interactions; four-stage, amphoteric redox behaviour is observed by cyclic voltammetry.

Full text of DOI:10.1039/c39920000401

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