Synthesis p. 2379 - 2382 (2010)
Update date:2022-07-30
Topics:
Crespo, Livia T. C.
Ribeiro, Rodrigo Da S.
De Mattos, Marcio C. S.
Esteves, Pierre M.
Halofluorination of alkenes with a new system (trihaloisocyanuric acids and HF-pyridine) results in the formation of vicinal halofluoroalkanes. The reaction is regioselective leading to Markovnikov-oriented products and the halofluorinated adducts follow anti-addition in the case of cyclohexene and 1-methylcyclohexene. Reaction yields range from 67-88%. Georg Thieme Verlag Stuttgart · New York.
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