Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base

DOI: 10.1016/S0040-4039(00)91654-X

Source and publish data:

Tetrahedron Letters p. 1485 - 1488 (1992)

Update date:2022-07-30

Topics: Transmetallation Product Isolation Oxidative Addition Reductive Elimination Ligand Exchange

Authors:

Ozawa, Fumiyuki

Kubo, Akihiko

Hayashi, Tamio

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Article abstract of DOI:10.1016/S0040-4039(00)91654-X

Reaction of 2,3-dihydrofuran with aryl triflate (1) in the presence of a base and a palladium catalyst, generated in situ from Pd(OAc)₂ and (R)-BINAP, gave (R)-2-aryl-2,3-dihydrofuran (2) and a small amount of (S)-2-aryl-2,5-dihydrofuran (3). T

Full text of DOI:10.1016/S0040-4039(00)91654-X

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