Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

DOI: 10.1016/S0040-4039(00)60467-7

Source and publish data:

Tetrahedron Letters p. 2867 - 2870 (1993)

Update date:2022-08-05

Topics:

Authors:

Funk, Raymond L.

Umstead-Daggett, Joy

Brummond, Kay M.

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Article abstract of DOI:10.1016/S0040-4039(00)60467-7

Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and tri substituted vinyl sulfones.

Full text of DOI:10.1016/S0040-4039(00)60467-7

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