Synthesis of (+/-)-Isopiperitenol by Fluoride Ion Mediated Cyclization of Allylsilane Moiety Incorporated in Terpene Aldehydes

DOI: 10.1246/bcsj.65.929

Source and publish data:

Bulletin of the Chemical Society of Japan p. 929 - 931 (1992)

Update date:2022-09-26

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Authors:

Nakamura, Hideshi

Oya, Toyohisa

Murai, Akio

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Article abstract of DOI:10.1246/bcsj.65.929

Fluoride ion mediated cyclization of aldehydes (1 and 2) having regioisomeric allylsilane functionalities gave a mixture of cis- and trans-isopiperitenol (3).The aldehydes (1) reacted faster and showed better stereoselectivity than the regioisomeric aldeh

Full text of DOI:10.1246/bcsj.65.929

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