Synthesis of (+/-)-Isopiperitenol by Fluoride Ion Mediated Cyclization of Allylsilane Moiety Incorporated in Terpene Aldehydes

DOI: 10.1246/bcsj.65.929

Source and publish data:

Bulletin of the Chemical Society of Japan p. 929 - 931 (1992)

Update date:2022-09-26

Topics:

Authors:

Nakamura, Hideshi

Oya, Toyohisa

Murai, Akio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.65.929

Fluoride ion mediated cyclization of aldehydes (1 and 2) having regioisomeric allylsilane functionalities gave a mixture of cis- and trans-isopiperitenol (3).The aldehydes (1) reacted faster and showed better stereoselectivity than the regioisomeric aldeh

Full text of DOI:10.1246/bcsj.65.929

Products guided by the article

Product name:benzyl (2E,6E)-3,7-dimethyl-8-dimethylphenylsilyl-8-phenylthio-2,6-octadienyl ether

Cas No:141245-03-6

R&D Labs maybe for 141245-03-6

Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Chengdu NoVi Biotechnology Co., Ltd.(expird)

Contact:13551243286/028-81458053

Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE
Amadis Chemical Co., Ltd.

website:http://www.amadischem.com

Contact:86-571-89925085

Address:Watts Cosine.No.166.Xiangmao Road.
Guarson Chemical Co., Ltd.

website:http://www.guarson.com

Contact:+86-523-88059600,+86-13805268803

Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China

Relevant to this article

A Convenient Synthesis of 9,9-Dialkyl-9,10-dihydroanthracenes and 10,10-Dialkylanthrones: Silicon-Mediated Regioselective Dialkylation of 9,10-Dihydroanthracene

Doi:10.1021/jo00036a029
(1992)
Bis-chelates of nickel(II) and copper(II) with an O,S-donor piperazine ligand

Doi:10.1007/s11243-018-0243-3
(2018)
Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides

Doi:10.1021/acscatal.7b03388
(2018)
Some synthetic applications of vinylphosphane oxides

Doi:10.1016/j.tet.2010.10.016
(2010)
Efficient palladium-catalyzed double arylation of phosphonoalkynes and diarylalkynes in water: Use of a dinuclear palladium(I) catalyst

Doi:10.1002/adsc.201000579
(2010)
Synthesis, characterization and properties of N-maleimide side-chain liquid crystalline copolymers

Doi:10.1002/pola.24463
(2011)

Article Doi