Journal of the Chemical Society. Chemical communications p. 488 - 490 (1992)
Update date:2022-09-26
Topics:
Kappe, C. Oliver
Kollenz, Gert
Netsch, Klaus-Peter
Leung-Toung, Regis
Wentrup, Curt
N-Adamantylimidoylketene 2 produced from pyrroledione 1 is in thermal equilibrium with azetin-2-one 4; 2 also thermally rearranges to oxoketenimine 3; azetin-2-one 4 is photolytically converted into imidoylketene 2, and thermally cleaved to adamantyl isocyanate 5 and 1-phenylpropyne 6.
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