The Use of Lewis Acids in Radical Chemistry. Chelation-Controlled Radical Reductions of Substituted α-Bromo-β-alkoxy Esters and Chelation-Controlled Radical Addition Reactions

DOI: 10.1021/jo980636x

Source and publish data:

Journal of Organic Chemistry p. 6554 - 6565 (1998)

Update date:2022-07-30

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Authors:

Guindon, Yvan

Rancourt

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Article abstract of DOI:10.1021/jo980636x

The radical reduction of a series of α-bromo-β-alkoxy esters under chelation-controlled conditions is reported. Proceeding with high stereoselectivity in the presence of MgBr₂middot;OEt₂, reductions give access to syn products. Syste

Full text of DOI:10.1021/jo980636x

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