Asymmetric induction in Aza-Claisen rearrangement of carboxamide enolates. Effect of chiral auxiliary on nitrogen

DOI: 10.1016/S0040-4039(00)91698-8

Source and publish data:

Tetrahedron Letters p. 1651 - 1654 (1992)

Update date:2022-08-05

Topics:

Authors:

Tsunoda, Tetsuto

Sakai, Mika

Sasaki, Osamu

Sako, Yoshie

Hondo, Yuka

Ito, Sho

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Article abstract of DOI:10.1016/S0040-4039(00)91698-8

Aza-Claisen rearrangement of enolates of N-alkyl-N-(2E)-butenylpropanamides with chiral alkyl groups proceeded with high relative asymmetric induction as well as excellent internal asymmetric induction to give optically active N-alkyl-Psyn-2,3-dimethylpen

Full text of DOI:10.1016/S0040-4039(00)91698-8

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