Asymmetric induction in Aza-Claisen rearrangement of carboxamide enolates. Effect of chiral auxiliary on nitrogen

DOI: 10.1016/S0040-4039(00)91698-8

Source and publish data:

Tetrahedron Letters p. 1651 - 1654 (1992)

Update date:2022-08-05

Topics:

Authors:

Tsunoda, Tetsuto

Sakai, Mika

Sasaki, Osamu

Sako, Yoshie

Hondo, Yuka

Ito, Sho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)91698-8

Aza-Claisen rearrangement of enolates of N-alkyl-N-(2E)-butenylpropanamides with chiral alkyl groups proceeded with high relative asymmetric induction as well as excellent internal asymmetric induction to give optically active N-alkyl-Psyn-2,3-dimethylpen

Full text of DOI:10.1016/S0040-4039(00)91698-8

Products guided by the article

Product name:(2S,3R)-2,3-Dimethyl-pent-4-enoic acid ((S)-2-methyl-1-phenyl-propyl)-amide

Cas No:141505-88-6

R&D Labs maybe for 141505-88-6

ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA

Relevant to this article

Cytotoxic 2-phenyacrylnitriles, the importance of the cyanide moiety and discovery of potent broad spectrum cytotoxic agents

Doi:10.1016/j.ejmech.2012.09.019
(2012)
Preparatory study for the synthesis of the starfish alkaloid imbricatine. Syntheses of 5-arylthio-3-methyl-L-histidines

Doi:10.1248/cpb.42.1784
(1994)
3-Phenyl substituted 6,7-dimethoxyisoquinoline derivatives as FtsZ-targeting antibacterial agents

Doi:10.1016/j.bmc.2012.10.009
(2012)
1,3-dipolar cycloaddition in a series of 7-oxoalkyl-1,3,7-triazapyrenium salts

Doi:10.1007/s10593-012-1100-5
()
Diastereoselective synthesis of the C17-C30 fragment of amphidinol 3

Doi:10.1039/c2ob26641e
(2012)
Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral α-branched heteroaryl amines

Doi:10.1016/j.tetlet.2012.09.131
(2012)

Article Doi