Asymmetric induction in Aza-Claisen rearrangement of carboxamide enolates. Effect of chiral auxiliary on nitrogen

DOI: 10.1016/S0040-4039(00)91698-8

Source and publish data:

Tetrahedron Letters p. 1651 - 1654 (1992)

Update date:2022-08-05

Topics:

Authors:

Tsunoda, Tetsuto

Sakai, Mika

Sasaki, Osamu

Sako, Yoshie

Hondo, Yuka

Ito, Sho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)91698-8

Aza-Claisen rearrangement of enolates of N-alkyl-N-(2E)-butenylpropanamides with chiral alkyl groups proceeded with high relative asymmetric induction as well as excellent internal asymmetric induction to give optically active N-alkyl-Psyn-2,3-dimethylpen

Full text of DOI:10.1016/S0040-4039(00)91698-8

Products guided by the article

Product name:(2S,3R)-2,3-Dimethyl-pent-4-enoic acid ((S)-2-methyl-1-phenyl-propyl)-amide

Cas No:141505-88-6

R&D Labs maybe for 141505-88-6

Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Changzhou Welton Chemical Co., Ltd,

Contact:0086-519-85910828,85920537,85912897

Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.

Relevant to this article

Cytotoxic 2-phenyacrylnitriles, the importance of the cyanide moiety and discovery of potent broad spectrum cytotoxic agents

Doi:10.1016/j.ejmech.2012.09.019
(2012)
Preparatory study for the synthesis of the starfish alkaloid imbricatine. Syntheses of 5-arylthio-3-methyl-L-histidines

Doi:10.1248/cpb.42.1784
(1994)
3-Phenyl substituted 6,7-dimethoxyisoquinoline derivatives as FtsZ-targeting antibacterial agents

Doi:10.1016/j.bmc.2012.10.009
(2012)
1,3-dipolar cycloaddition in a series of 7-oxoalkyl-1,3,7-triazapyrenium salts

Doi:10.1007/s10593-012-1100-5
()
Diastereoselective synthesis of the C17-C30 fragment of amphidinol 3

Doi:10.1039/c2ob26641e
(2012)
Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral α-branched heteroaryl amines

Doi:10.1016/j.tetlet.2012.09.131
(2012)

Article Doi