Metal Ion Controlled Addition to α,β-Dialkoxy Carbonyl Compounds

DOI: 10.1021/jo00203a040

Source and publish data:

Journal of Organic Chemistry p. 422 - 424 (1985)

Update date:2022-08-02

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Authors:

Mead, Keith

Macdonald, Timothy L.

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Article abstract of DOI:10.1021/jo00203a040

Complementary stereoselection in the addition of carbon and hydride nucleophiles to α,β-dialkoxy carbonyl systems can be obtained with Mg²⁺-based (syn addition) and Li⁺- and Ti⁴⁺-based (anti addition) reagents.

Full text of DOI:10.1021/jo00203a040

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