CHBr3/TiCl4/Mg as an unusual nucleophilic CBr 2 carbenoid: Effective and chemoselective dibromomethylenation of aldehydes and ketones

DOI: 10.1002/ejoc.201200457

Source and publish data:

European Journal of Organic Chemistry p. 4805 - 4810 (2012)

Update date:2022-07-29

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Authors:

Bhorge, Yeshwant Ramchandra

Chang, Cheng-Ta

Chang, Su-Haur

Yan, Tu-Hsin

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Article abstract of DOI:10.1002/ejoc.201200457

We report that instead of using CBr₄, CHBr₃ can serve as a highly nucleophilic dibromomethylene carbenoid in chemoselective carbonyl dibromomethylenation. Successful application of the dibromomethylenation to various carbonyl compoun

Full text of DOI:10.1002/ejoc.201200457

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