Journal of Organic Chemistry p. 3765 - 3766 (1992)
Update date:2022-08-04
Topics:
Xia, Haiji
Moore, Harold W.
4-(1,5-Dialkynyl)-4-methoxycyclobutenones 1 were shown to undergo a unique rearrangement to annelated spiroepoxides 6 upon thermolysis in toluene.The 4-hydroxy analogs also ring expand giving either quinones 13 or 14 as a function of the reaction solution
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