Long Distance Intramolecular Photoinduced Electron Transfer in Donor-Acceptor Systems: Effect of Exothermicity on Electron-transfer Rates

DOI: 10.1039/c39920000669

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 669 - 670 (1992)

Update date:2022-07-29

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Authors:

Zhou, Scheng-ze

Schen, Shu-yin

Zhou, Qing-fu

Xu, Hui-jun

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Article abstract of DOI:10.1039/c39920000669

Photoinduced intramolecular electron transfer in donor-acceptor systems separated by a long distance are studied by fluorescence quenching experiments; reduced rate constants for electron transfer are observed in highly exothermic reactions, which indicates the existence of an 'inverted region', in accord with Marcus' model.

Full text of DOI:10.1039/c39920000669

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