Mechanism of the gustavson rearrangement. Reaction of tetrahaloneopentanes, esters of tribromoneopentanol and their cyclopropyl analogs with zinc.

DOI: 10.1016/S0040-4039(01)86261-4

Source and publish data:

Tetrahedron Letters p. 2055 - 2058 (1979)

Update date:2022-09-26

Topics:

Authors:

Dyachenko

Protasova

Ioffe Ioffe

Steinschneider

Nefedov Nefedov

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Article abstract of DOI:10.1016/S0040-4039(01)86261-4

The formation of methylenecyclobutane in the reaction of tetrahaloneopentanes and related compounds with zinc is shown to proceed via organozinc intermediates.

Full text of DOI:10.1016/S0040-4039(01)86261-4

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