A Novel Deacylation Method using Grignard Reagent without affecting the Neighbouring Base-sensitive Functional Groups

DOI: 10.1039/c39920000681

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 681 - 683 (1992)

Update date:2022-08-04

Topics:

Authors:

Watanabe, Yutaka

Fujimoto, Takahiro

Ozaki, Shoichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000681

Methyl and ethyl Grignard reagents are shown to cleave ester functions such as benzoate and acetate without affecting the neighbouring base-sensitive functional groups.

Full text of DOI:10.1039/c39920000681

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Phosphoric acid, 3-hydroxy-1-methylpropyl bis(phenylmethyl) ester

Cas No:142072-08-0

R&D Labs maybe for 142072-08-0

Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China

Relevant to this article

First one-pot organocatalytic synthesis of α-methylene-γ- lactones

Doi:10.1039/c2cc38659c
(2013)
Antimalarial activity of 10-alkyl/aryl esters and -aminoethylethers of artemisinin

Doi:10.1016/j.bioorg.2012.10.002
(2013)
The total synthesis of swinholide A. Part 1 : A stereocontrolled synthesis of a C19-C32 segment

Doi:10.1016/0040-4020(95)00546-K
(1995)
Aqua mediated one pot facile synthesis of novel thioxo-1,2,4-triazin-5(2H)- one and [1,2,4] triazino[5,6-b]indole derivatives and their biological activities

Doi:10.4067/S0717-97072012000400004
(2012)
Reactions of platinum(II) aqua complexes. 1. Multinuclear (¹⁹⁵Pt, ¹⁵N, and ³¹P) NMR study of reactions between the cis-diamminediaquaplatinum(II) cation and the oxygen-donor liga

Doi:10.1021/ic00190a016
(1984)
First keto-functionalized microporous Al-based metal-organic framework: [Al(OH)(O₂C-C₆H₄-CO-C₆H ₄-CO₂)]

Doi:10.1021/ic301961q
(2013)

Article Doi