A Novel Deacylation Method using Grignard Reagent without affecting the Neighbouring Base-sensitive Functional Groups

DOI: 10.1039/c39920000681

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 681 - 683 (1992)

Update date:2022-08-04

Topics:

Authors:

Watanabe, Yutaka

Fujimoto, Takahiro

Ozaki, Shoichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000681

Methyl and ethyl Grignard reagents are shown to cleave ester functions such as benzoate and acetate without affecting the neighbouring base-sensitive functional groups.

Full text of DOI:10.1039/c39920000681

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Phosphoric acid, 3-hydroxy-1-methylpropyl bis(phenylmethyl) ester

Cas No:142072-08-0

R&D Labs maybe for 142072-08-0

Guangxi Shanyun Biochemical Science and Technology Co., Ltd

Contact:+86-0772--6828887

Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
Zhejiang Quzhou Jiancheng Silicone Co., Ltd.(Shanghai Jiancheng Industial and Trade Co, Ltd)

Contact:18957018777 +86-570-3888777

Address:The company production base address： Quzhou City, Zhejiang Province high-tech industrial park Nianhua Road 37

Relevant to this article

First one-pot organocatalytic synthesis of α-methylene-γ- lactones

Doi:10.1039/c2cc38659c
(2013)
Antimalarial activity of 10-alkyl/aryl esters and -aminoethylethers of artemisinin

Doi:10.1016/j.bioorg.2012.10.002
(2013)
The total synthesis of swinholide A. Part 1 : A stereocontrolled synthesis of a C19-C32 segment

Doi:10.1016/0040-4020(95)00546-K
(1995)
Aqua mediated one pot facile synthesis of novel thioxo-1,2,4-triazin-5(2H)- one and [1,2,4] triazino[5,6-b]indole derivatives and their biological activities

Doi:10.4067/S0717-97072012000400004
(2012)
Reactions of platinum(II) aqua complexes. 1. Multinuclear (¹⁹⁵Pt, ¹⁵N, and ³¹P) NMR study of reactions between the cis-diamminediaquaplatinum(II) cation and the oxygen-donor liga

Doi:10.1021/ic00190a016
(1984)
First keto-functionalized microporous Al-based metal-organic framework: [Al(OH)(O₂C-C₆H₄-CO-C₆H ₄-CO₂)]

Doi:10.1021/ic301961q
(2013)

Article Doi