Synthesis of fluoroalkyl ethanal: R(F)CH2CHO

DOI: 10.1016/S0040-4039(00)92222-6

Source and publish data:

Tetrahedron Letters p. 2489 - 2492 (1992)

Update date:2022-08-04

Topics:

Authors:

Laurent Laurent

Blancou Blancou

Commeyras

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Article abstract of DOI:10.1016/S0040-4039(00)92222-6

Aldehydes R(F)CH₂CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. R(F)CH₂CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, R(F)CH₂CHO and its acylal or acetal derivatives are obtained in good yields.

Full text of DOI:10.1016/S0040-4039(00)92222-6

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