Synthesis and reactivity of benzylic and allylic samarium compounds

DOI: 10.1016/S0040-4020(01)88468-4

Source and publish data:

Tetrahedron p. 3877 - 3890 (1992)

Update date:2022-08-03

Topics:

Authors:

Bied Bied

Collin Collin

Kagan Kagan

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Article abstract of DOI:10.1016/S0040-4020(01)88468-4

Benzyl and allyl samarium species are prepared by reaction of benzylic or allylic chlorides with SmCp₂. They present a wide scope of reactivity towards aldehydes, ketones and acid chlorides.

Full text of DOI:10.1016/S0040-4020(01)88468-4

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