Isomerization of alkynemono-ols catalyzed by palladium(0) complex and diols

DOI: 10.1016/0022-328X(92)83235-A

Source and publish data:

Journal of Organometallic Chemistry p. 259 - 266 (1992)

Update date:2022-07-30

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Authors:

Lu, Xiyan

Ji, Jianguo

Guo, Cheng

Shen, Wei

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Article abstract of DOI:10.1016/0022-328X(92)83235-A

Isomerization of alkynemono-ols occurred by the catalysis of Pd2(dba)3 * CHCl3 (1) + ⁱPr3P + HOCH2CH2OH.Palladium hydride active species were supposed to be formed in situ by the oxidative addition of diols to 1 as determined bu 1H NMR spectra.

Full text of DOI:10.1016/0022-328X(92)83235-A

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