Asymmetric Alkylation Using Chiral Cyclic Diols to Prepare a Quaternary Carbon

DOI: 10.1016/S0040-4020(01)87012-5

Source and publish data:

Tetrahedron p. 3315 - 3326 (1994)

Update date:2022-09-26

Topics:

Authors:

Kato, Keisuke

Suemune, Hiroshi

Sakai, Kiyoshi

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Article abstract of DOI:10.1016/S0040-4020(01)87012-5

Asymmetric alkylation of cyclic and acyclic β-keto ester acetals (4, 5, 13, 14, and 18) with C₂-symmetric cycloalkane-1,2-dioxy moiety proceeded in a highly diastereoselective manner to afford enol ethers (9-12, 15-17, 19a-c) with a chiral quat

Full text of DOI:10.1016/S0040-4020(01)87012-5

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