A Short, Chirospecific Synthesis of the Ant Venom Alkaloid (3R,5S,8S)-3,5-Dialkylpyrrolizidines

DOI: 10.1021/jo00042a017

Source and publish data:

Journal of Organic Chemistry p. 4401 - 4404 (1992)

Update date:2022-08-03

Topics:

Authors:

Takahata, Hiroki

Bandoh, Hiroshi

Momose, Takefumi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00042a017

The stereospecific synthesis of both (+)-xanovenine (1) and (+)-(3R,5S,8S)-3-methyl-5-(8-nonenyl)pyrrolizidine (2) found in ant venom, is described.The stereoselective intramolecular amidomercuration of the N-alkenylurethane 3, available from D-alanine, f

Full text of DOI:10.1021/jo00042a017

Products guided by the article

Product name:Phosphonic acid, [2-oxo-10-(phenylmethoxy)decyl]-, dimethyl ester

Cas No:143064-42-0

R&D Labs maybe for 143064-42-0

New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
MedicalChem(Yancheng)Manuf.Co.,Ltd.

Contact:+86-515-84383366

Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai

Relevant to this article

Reactivity of o-Styryl Oxazolines with Nucleophiles

Doi:10.1021/jo00046a004
(1992)
Synthesis of (3S)-(tert-butyldimethylsilyloxy)methylcyclopentan-1-one as a key intermediate of sphingosine 1-phosphate-1 receptor agonists

Doi:10.1016/j.tetasy.2013.02.015
(2013)
Regioselective buta-1,3-dienylation of aldehydes via transmetallation of 2-tributylstannylbuta-1,3-diene

Doi:10.1055/s-1999-2787
(1999)
N-Isocyanimino-Triphenylphosphorane (Ph 3Pnnc) as an Efficient Reagent for the Preparation of Fully Substituted 1,3,4-Oxadiazoles via Intramolecular Aza-Wittig Reaction in Water

Doi:10.1080/10426507.2015.1054486
(2015)
One-pot synthesis of 13-acetyl-9-methyl-11-oxo(or thioxo)-8-oxa-10,12- diazatricyclo[7.3.1.0^2,7]trideca-2,4,6-trienes under microwave irradiation

Doi:10.1002/jhet.978
(2012)
Discovery of highly potent DPP-4 inhibitors by hybrid compound design based on linagliptin and alogliptin

Doi:10.1016/j.ejmech.2014.06.044
(2014)

Article Doi