A Short, Chirospecific Synthesis of the Ant Venom Alkaloid (3R,5S,8S)-3,5-Dialkylpyrrolizidines

DOI: 10.1021/jo00042a017

Source and publish data:

Journal of Organic Chemistry p. 4401 - 4404 (1992)

Update date:2022-08-03

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Authors:

Takahata, Hiroki

Bandoh, Hiroshi

Momose, Takefumi

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Article abstract of DOI:10.1021/jo00042a017

The stereospecific synthesis of both (+)-xanovenine (1) and (+)-(3R,5S,8S)-3-methyl-5-(8-nonenyl)pyrrolizidine (2) found in ant venom, is described.The stereoselective intramolecular amidomercuration of the N-alkenylurethane 3, available from D-alanine, f

Full text of DOI:10.1021/jo00042a017

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