A Divergent Entry into Prostaglandin Synthesis through 1,4-Addition of Methoxy(phenylthio)(trimethylsilyl)methyllithium to 4-Siloxy-2-cyclopentenone

DOI: 10.1016/S0040-4039(00)92528-0

Source and publish data:

Tetrahedron Letters p. 3655 - 3658 (1992)

Update date:2022-07-30

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Authors:

Otera, Junzo

Niibo, Yoshihisa

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(00)92528-0

1,4-Addition of methoxy(phenylthio)(trimethylsilyl)methyllithium to 4-siloxy-2-cyclopentenone followed by in situ alkylation of the resulting enolate provides a versatile intermediate for synthesis of prostaglandins.

Full text of DOI:10.1016/S0040-4039(00)92528-0

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Product name:5-Heptenoic acid, 7-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-[methoxy(phenylthio)(trimeth ylsilyl)methyl]-5-oxocyclopentyl]-, methyl ester

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