An efficient construction of 1,2-trans-β-glycosidic linkages capitalizing on glycopyranosyl N,N,N',N'-tetramethylphosphoroamidates as shelf-stable glycosyl donors

Article abstract of DOI:10.1016/S0040-4039(00)92679-0

A highly stereocontrolled 1,2-trans-β-glycosidation reaction with or without neighbouring group participation has been developed by using benzyl- or benzoyl-protected glycopyranosyl N,N,N',N'-tetramethylphosphoramidates as shelf-stable glycosyl donors in