Co(salen) catalyzed oxidation of 2,4,6-trisubstituted anilines with tert-butylhydroperoxide

DOI: 10.1016/S0040-4039(00)60100-4

Source and publish data:

Tetrahedron Letters p. 4425 - 4428 (1992)

Update date:2022-08-04

Topics: Catalyzed oxidation

Authors:

Nishinaga

Forster Forster

Eichhorn

Speiser Speiser

Rieker Rieker

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Article abstract of DOI:10.1016/S0040-4039(00)60100-4

Co(salen) catalyzed oxidation of 2,4,6-trisubstituted (preferentially 2,6-di-tert-butylated) anilines with tert-butylhydroperoxide gives 4-tert-butylperoxy-2,5-cyclohexadien-1-imine and nitrobenzene derivatives. The relative ratio of the products depends on the nature of the substituents in the substrate.

Full text of DOI:10.1016/S0040-4039(00)60100-4

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Product name:2,5-Cyclohexadien-1-imine, 2,6-bis(1,1-dimethylethyl)-4-[(1,1-dimethylethyl)dioxy]-4-phenyl-

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