The synthesis and thermodynamic equilibrium of eight 5-O-benzyl-2 (or 3)-dimethylamino-3 (or 2)-o-mesyl-α (or β)-d-xylo (or arabino) methylfuranosides

Article abstract of DOI:10.1016/S0040-4020(01)90122-X

Regioselectivity of the opening of 2,3-anhydrofuranosides 1 (α and β) and 2 (α and β) by dimethylamine (and by ammonia for 1) has been determined. Thermic stability of the eight corresponding vic-dimethylaminomesylates 11-14 (α and β) in CD₃CN